THINK_ IMAGINE_ QUESTION_ TRY ANSWERING_IN A Che’MYSTERY WORLD
For no particular reason I just transferred my household
salt (iodized) into a dry jar. Instantly noticed the net weight as 1 kilogram. I
thought of how many molecules of potassium iodate (KIO3) it holds
in, how many atoms of potassium, iodine and oxygen it has…and lot more questions
were circulating in mind. To give a response, I tried out with MOLE concept. It
may sound strange to a non-chemist. It’s actually a counting. To make it very simple
I can say a dozen banana means 12 bananas similar way a mole of chocolate means
6.023*1023 chocolates, a funny and weird thing! Ok, now all we have
to do is to learn few conversions as follows:
1 mole= 6.023*1023
particles (a huge number) = 602300000000000000000000 particles
1 mole= gram equivalent weight
1 mole= 22.4
The solution goes like π
Step 1: convert kg to g (1 kg= 1000 g)
1 kg * 1000 g / 1 kg = 1000 g
Step 2: convert g to mole (1 mole= gram equivalent weight)
Gram equivalent
of KIO3= 39.0983
126.90447
3(15.999)= +
47.997
213.99977 g
Now, 1000 g*1 mole/ 213.99977 g= 4.6729 mole
Step 3: convert mole to molecules (1 mole= 6.023*1023
molecules)
4.6729 mole*6.023*1023/
1 mole= 2.81448767*1024 molecules (approximately 3*1024 molecules)
Therefore, there are 3*1024 molecules of
potassium iodate in 1kilogram of that household salt.
Alternative method:
|
No. of potassium |
1(6.023*1023) |
6.023*1023 atoms |
|
No. of iodine |
1(6.023*1023) |
6.023*1023 atoms |
|
No. of oxygen |
3(6.023*1023) |
1.8069*1024 atoms |
|
Total |
|
3.0115*1024 molecules |
In addition, I noticed ‘iodine content above 15 ppm’ underneath the ingredients.
I knew that parts per million is one of the concentration term which is abbreviated as PPM. It is more applicable to dilute solution i.e., solvent containing trace amount of solute. You may ask me that what does concentration terms mean by? It is all related with solution where there we find the quantity or the amount of solute dissolved in a solvent. Okay at this moment we will discuss about the statement iodine content above 15 ppm. Firstly, 15 ppm is nothing but 15 grams of solute in 106 grams (1 million) of solution. To find the iodine content in ppm of my salt, I just picked up the needed data from the tabulation saying nutritional information and loaded them in my formula. It says that “nutritional information per 100 grams” that means the weight of solution is 100 g and the amount of iodine per 100 g is 2 mg (also given).
We know, 1 gram= 1000 milligram
So the weight of solution= 100 g
And the weight of iodine per 100 g= 0.002 g
PARTS PER MILLION= weight of solute/ weight of solution * 106
PARTS PER MILLION= 0.002 g/ 100 g * 106
PARTS PER MILLION=
20 parts per million (obviously the value of iodine in ppm is above 15).
Therefore, my household salt iodine content is roughly 20
ppm.
For accurate result we can adopt iodometric titration and
report the value in parts per million.
In General, Iodine is required for normal growth, thyroid
and brain function. Also helps in mental development of children. πWe must
always ensure the amount of iodine must range from 15-40 parts per million (recommended by World Health Organization).



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